| A. Chemicals that form explosive levels of peroxides without concentration |
| Butadienea |
Isopropyl ether |
Sodium amide (sodamide) |
| Chloroprenea |
Potassium metal |
Tetrafluoroethylenea |
| Divinylacetylene |
Potassium amide |
Vinylidene chloride |
| |
| B. Chemicals that form explosive levels of peroxides on concentration |
| Acetal |
Diethyl ether |
4-Methyl-2-pentanol |
| Acetaldehyde |
Diethylene glycol dimethyl |
2-Pentanol |
| ether (diglyme) |
| Benzyl alcohol |
Dioxanes |
4-Penten-1-ol |
| 2-Butanol |
Ethylene glycol dimethyl |
1-Phenylethanol |
| ether (glyme) |
| Cumene |
4-Heptanol |
2-Phenylethanol |
| 2-Cyclohexen-1-ol |
2-Hexanol |
2-Propanol |
| Cyclohexene |
Methylacetylene |
Tetrahydrofuran |
| Decahydronaphthalene |
3-Methyl-1-butanol |
Tetrahydronaphthalene |
| Diacetylene |
Methylcyclopentane |
Vinyl ethers |
| Dicyclopentadiene |
Methyl isobutyl ketone |
Other secondary alcohols |
| |
| C. Chemicals that may autopolymerize as a result of peroxide accumulation |
| Acrylic acidb |
Methyl methacrylateb |
Vinyl chloride |
| Acrylonitrileb |
Styrene |
Vinylpyridine |
| Butadienec |
Tetrafluoroethylenec |
Vinyladiene chloride |
| Chloroprenec |
Vinyl acetate |
|
| Chlorotrifluoroethylene |
Vinylacetylene |
|
| |
| D. Chemicals that may form peroxides but cannot clearly be placed in sections A-C |
| Acrolein |
p-Chlorophenetole |
4,5-Hexadien-2-yn-1-ol |
| Allyl etherd |
Cyclooctened |
n-Hexyl ether |
| Allyl ethyl ether |
Cyclopropyl methyl ether |
o,p-Iodophenetole |
| Allyl phenyl ether |
Diallyl etherd |
Isoamyl benzyl etherd |
| p-(n-Amyloxy)benzoyl |
p-Di-n-butoxybenzene |
Isoamyl etherd |
| chloride |
| n-Amyl ether |
1,2-Dibenzyloxyethaned |
Isobutyl vinyl ether |
| Benzyl n-butyl etherd |
p-Dibenzyloxybenzened |
Isophoroned |
| Benzyl etherd |
1,2-Dichloroethyl ethyl |
B-Isopropoxypropionitriled |
| Ether |
| Benzyl ethyl etherd |
2,4-Dichlorophenetole |
Isopropyl 2,4,5-trichloro- |
| phenoxy- acetate |
| Benzyl methyl ether |
Diethoxymethaned |
Limonene |
| Benzyl 1-napthyl etherd |
2,2-Diethoxypropane |
1,5-p-Methadiene |
| 1,2-Bis(2-chloroethoxy) |
Diethyl ethoxymethylene- |
Methyl p-(n-amyloxy)- |
| Ethane |
Malonate |
benzoate |
| Bis(2 ethoxyethyl)ether |
Diethyl fumarated |
4-Methyl-2-pentanone |
| Bis(2-(methoxyethoxy)- |
Diethyl acetald |
n-Methylphenetole |
| ethyl) ether |
| Bis(2-chloroethyl)ether |
Diethyketenef |
2-Methyltetrahydrofuran |
| Bis(2-ethoxyethyl)adipate |
m,o,p-diethoxybenzene |
3-Methoxy-1-butyl acetate |
| Bis(2-ethoxyethyl)phthalate |
1,2-Diethoxyethane |
2-Methoxyethanol |
| Bis(2-methoxyethyl)- |
Dimethoxymethaned |
3-Methoxyethyl acetate |
| Carbonate |
| Bis(2-methoxyethyl) ether |
1,1-Dimethoxyethaned |
2-Methoxyethyl vinyl ether |
| Bis(2-methoxyethyl) |
Dimethylketenef |
Methonxy-1,3,5,7-cyclo- |
| Phthalate |
octa-tetraene |
| Bis(2-methoxymethyl) |
3,3-Dimethoxypropene |
B-Methoxypropionitrile |
| Adipate |
| Bis(2-n-butoxyethyl) |
2,4-Dinitrophenetole |
m-Nitrophenetole |
| Phthalate |
| Bis(2-phenoxyethyl) ether |
1,3-Dioxepaned |
1-Octene |
| Bis(4-chlorobutyl) ether |
Di(1-propynyl)etherf |
Oxybis(2-ethyl acetate) |
| Bis(chloromethyl) ethere |
Di(2-propynyl)ether |
Oxybis(2-ethyl benzoate) |
| 2-Bromomethyl ethyl ether |
Di-n-propoxymethaned |
B,B-oxydipropionitrile |
| B-Bromophenetole |
1,2-Epoxy-3-isopropoxy- |
1-Pentene |
| propaned |
| o-Bromophenetole |
1,2-Epoxy-3-phenoxy- |
Phenoxyacetyl chloride |
| propane |
| p-Bromophenetole |
p-Ethoxyacethophenone |
a-Phenoxypropionyl chloride |
| 3-Bromopropyl phenyl ether |
2-Ethoxyethyl acetate |
Phenyl o-propyl ether |
| 1,3-Butadiyne |
(2-Ethoxyethyl)-o-benzoyl |
p-Phenylphenetone |
| benzoate |
| Buten-3-yne |
1-(2-Ethoxyethoxy)ethyl |
n-Propyl ether |
| acetate |
| tert-Butyl ethyl ether |
1-Ethoxynaphthalene |
n-Propyl isopropyl ether |
| tert-Butyl methyl ether |
o,p-Ethoxyphenyl |
Sodium 8,11,14-eicosa- |
| isocyanate |
tetraenoate |
| |
|
| n-Butyl phenyl ether |
1-Ethoxy-2-propyne |
Sodium ethoxyacetylidef |
| n-Butyl vinyl ether |
3-Ethoxyopropionitrile |
Tetrahydropyran |
| Chloroacetaldehyde |
2-Ethylacrylaldehyde oxime |
Triethylene glycol diacetate |
| diethylacetald |
| 2-Chlorobutadiene |
2-Ethylbutanol |
Triethylene glycol diprop- |
| ionate |
| 1-(2-Chloroethoxy)-2- |
Ethyl B-ethoxypropionate |
1,3,3-Trimethoxypropened |
| phen-oxyethane |
| Chloroethylene |
2-Ethylhexanal |
1,1,2,3-Tetrachloro-1,3- |
| butadiene |
| Chloromethyl methyl ethere |
Ethyl vinyl ether |
4-Vinyl cyclohexene |
| B-Chlorophenetole |
Furan |
Vinylene carbonate |
| o-Chlorophenetole |
2,5-Hexadiyn-1-ol |
Vinylidene chlorided |
| |
| NOTES: |
| a When stored as a liquid monomer. |
| b Although these chemicals form peroxides, no explosions involving these |
| monomers have been reported. |
| c When stored in liquid form, these chemicals form explosive levels of peroxides |
| without concentration. They may also be stored as a gas in gas cylinders. |
| When stored as a gas, these chemicals may autopolymerize as a result of |
| peroxide accumulation. |
| d These chemicals easily form peroxides and should probably be considered |
| under Part B. |
| e OSHA - regulated carcinogen. |
| f Extremely reactive and unstable compound. |
